It's about Milk and Sugar
When we talk about about a coffee high in calories - we are really talking about the additives we put in it. Caffeine is a bitter chemical and products containing caffeine are bitter - so we tend to sweeten them up - with milk, sugar, or syrups.The larger the drink volume - the more milk you will be getting. With espresso-based drinks (latte, cappuccino) - the amount of water in the drink is minimal (typically 45mls / 1.5 fl. ounces per espresso shot). You do the math: a 16 ounces Grande Latte from Starbucks will have two espresso shots (~ 3 oz) -- that leaves around 13 ounces of milk (depending on how much foam tops the drink) - so there's 198 Calories already (if the milk is 2% reduced fat).
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